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This brief reviews the functions, recent developments, challenges and prospects of the Li/S and Li/O 2 batteries, including the fundamental knowledge, research status, potential applications etc. It starts with a brief overview and encompasses the current state of Li/S and Li/O 2 battery technology. Then it provides the basic knowledge about Li/S and Li/O 2 batteries, including the electrochemical processes and the battery components. The following chapters focus on the historical and recent development of the Li/S and Li/O 2 batteries respectively, giving detailed information about the key materials development, cell assembly, testing diagnosis and degradation mechanism. Finally, the main potential applications of Li/S and Li/O 2 batteries together with their challenge and perspectives are discussed.§§