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The book deals with state-of-the-art techniques available in the present time to explore rusting of steel reinforcement in concrete environment infinitesimally. The idea of the book is to grasp the concept of passive layer, its breakdown, rusting of steel and the interface between steel and concrete at the grass root level so that the original facts and figures can be understood. The books deals with the hands on experience, problems, solutions, case to case variations and limitations while using infinitesimal techniques for analyzing corrosion process in reinforced concrete structures. This is part I of the subject under consideration and will be followed by part II in the near future.